Avmaxvip ewbhnangopaimmiiokhsnaa Book Archive

Inorganic

Download e-book for kindle: Acid Derivatives: Volume 1 (1979) by

ISBN-10: 0470771585

ISBN-13: 9780470771587

ISBN-10: 0471996106

ISBN-13: 9780471996101

Content:
Chapter 1 contemporary advances within the theoretical remedy of acid derivatives (pages 1–58): I. G. Csizmadia, M. R. Peterson, C. Kozmutza and M. A. Robb
Chapter 2 Thermochemistry of acid derivatives (pages 59–66): Robert Shaw
Chapter three Chiroptical houses of acid derivatives (pages 67–120): Rolf Hakansson
Chapter four Mass spectra of acid derivatives (pages 121–174): S. W. Tam
Chapter five Complexes of acid anhydrides (pages 175–212): R. Foster
Chapter 6 Hydrogen bonding in carboxylic acids and derivatives (pages 213–266): Dusan Hadzi and Snegulka Detoni
Chapter 7 The synthesis of carboxylic acids and esters and their derivatives (pages 267–490): Michael A. Ogliaruso and James F. Wolfe
Chapter eight The chemistry of lactones and lactams (pages 491–531): G. V. Boyd
Chapter nine The chemistry of orthoamides of carboxylic acids and carbonic acid (pages 533–599): W. Kantlehner
Chapter 10 Detection and resolution of acid derivatives (pages 601–640): W. H. Prichard
Chapter eleven The photochemistry of natural acids, esters, anhydrides, lactones and imides (pages 641–753): Richard S. Givens and Nissim Levi

Show description

Read Online or Download Acid Derivatives: Volume 1 (1979) PDF

Best inorganic books

Download e-book for iPad: Handbook on the Physics and Chemistry of Rare Earths. vol.17 by G.R. Choppin, L. Eyring, G.H. Lander

This quantity of the guide is the 1st of a 3 quantity set of studies dedicated to the interrelationships, similarities, variations and contrasts of the lanthanide and actinide sequence of parts. so that it will comprehensively conceal this huge box prime scientists, G. H. Lander and G. R. Choppin, have been invited to be visitor editors for this distinct set of volumes.

Download PDF by Gerhard Czack, Gerhard Kirschstein, Wolfgang Kurtz, Frank: W Tungsten: Supplement Volume A4 Surface Properties.

The quantity describes actual houses of tungsten steel and covers in particular floor homes, electron emission, and box evaporation. Tungsten surfaces are essentially the most generally studied steel surfaces. lately, experimentalists and theorists have focussed their curiosity at the atomic constitution, lattice dynamics, and digital houses of the W(100) floor.

Fabio Doctorovich, Patrick J. Farmer, Marcelo A. Marti's The Chemistry and Biology of Nitroxyl (HNO) PDF

The Chemistry and Biology of Nitroxyl (HNO) offers first-of-its-kind insurance of the exciting biologically energetic molecule referred to as nitroxyl, or azanone in step with IUPAC nomenclature, which has been routinely elusive because of its intrinsically excessive reactivity. this beneficial source presents the medical foundation to appreciate the chemistry, biology, and technical features had to take care of HNO.

Extra info for Acid Derivatives: Volume 1 (1979)

Sample text

0a6 kcal/mole. N-methylacetamide (NMA) (1 1) was studied by Shipman and Christoffersen6 s , using floating spherical gaussian orbitals (FSGO). The lowest energy was obtained f o r a conformation with the N-methyl group cis t o the carbonyl group, a C-methyl group hydrogen eclipsing the CO group, and an N-methyl group hydrogen eclipsing the C-N bond. This C-N bond conformation was also found experimentally8 '. 66 kcal/ mole less stable. 8 kcal/moles5. Note that the conformational behaviour of the N-methyl group upon rotation about the C-N bond is opposite to that of NMF.

The fully extended form (1 80",180") was 4 kcal/mole less stable. IV. CHEMICAL PROPERTIES A. Protonation, Deprotonation and Proton Transfer Consecutive protonation and deprotonation reactions allow one to relate the acidity and basicity of compounds: A:- 1 AH 2 + Step 1 Sfep1 Step 2 S t e p 2' AH2' 2' 1' measures measures measures measures t h e basicity of A-. the acidity of AH. the basicity of AH. t h e acidity of AH;. The energy changes in reactions 1 o r 2 are given by P A , the proton affinity of A - or A H with a positive o r negative sign according t o the thermodynamic convention.

Reproduced with permission from A. C . Hopkinson and 1. G. Csizmadia, 7heoref. Cltim. , 31, 83 (1973). 1. Recent advances in the theoretical treatment of acid derivatives 49 0 W 0 -2c E \ - s -4c Y $ -6C 5 -8C lx w w t- a -1OC J 2 -12C -14C FIGURE 22. Computed reaction profile for the attack of OH- on formamide. Reproduced with permission from G. Alagona, E. Scrocco and J. Tomasi. J. Amer. Uzem. , 97, 6976 (1975). An ab initio s t u d y o n the base-catalysed hydrolysis of methyl formate has recently been reported' 2 3 involving the mechanism shown in equation (6 I ) .

Download PDF sample

Acid Derivatives: Volume 1 (1979)


by Brian
4.3

Rated 4.56 of 5 – based on 6 votes