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An Introduction to Co-ordination Chemistry by D. P. Graddon, H. Taube, A. G. Maddock PDF

By D. P. Graddon, H. Taube, A. G. Maddock

ISBN-10: 0080032370

ISBN-13: 9780080032375

An creation to Co-Ordination Chemistry, moment version covers the basic facets of co-ordination chemistry. The name is designed to introduce the readers to the fundamental ideas and theories that govern co-ordination chemistry.
The textual content first stories the background of co-ordination chemistry, after which proceeds to discussing the fashionable theories of co-ordination chemistry. subsequent, the choice covers transition steel stereochemistry. bankruptcy IV talks in regards to the balance of advanced salts, whereas bankruptcy V bargains with the stabilization of oxidation states. The textual content additionally covers carbonyls and II-complexes. within the final bankruptcy, the name provides the sensible purposes of co-ordination chemistry.
The e-book could be of significant use to scholars, researchers, and practitioners of chemistry similar disciplines.

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Table 1 gives Pauling's values of these ionic radii; while these values probably need revising in the light of the rapidly increasing amount of X-ray data, they show clearly the relationship of the size of these ions relative to those of neighbouring elements. WHILE TABLE 1. , p. 518. 55 Mg AI 0-74 0-65 - 0-50 0-50 56 AN INTRODUCTION TO CO-ORDINATION CHEMISTRY The ionization energies of these elements are also comparable (Table 2), so that differences of co-ordination number can rarely be attributed to the needs of the electroneutrality principle (see Chapter IV).

It may then happen that, due to the proximity of the paramagnetic centres, new energy levels may become available in which the electrons can be paired up, thus lowering the magnetic moment. An example of this occurs in the nickel(II) fluoride complex KNiF 3 ; the spin-only value of the moment would be 2-83/3, but the observed value is only 2-1/3. If the neighbouring nickel atoms are separated by isomorphous incorporation of zinc into the crystal, the moment rises to 2-8)8 as expected. Many transition metal oxides and halides, in which the low ratio of non-metal atoms to metal atoms inevi­ tably leads to proximity of the metal atoms to one another, have low moments.

An Introduction to the Chemistry of Transition Metals, Methuen, London (1960). , Cornell University Press, New York (1960). SELWOOD, P. , Interscience, New York (1956). , VISTE, A. and GRAY, H. , Molecular orbital theory for octahedral and tetrahedral metal complexes, J. Chem. Phys. 44, 10(1966). COTTON, F. , The infrared spectra of transition metal complexes. Modern Coordination Chemistry, Eds. LEWIS, J. and WILKINS, R. , Interscience, New York (1960). CRAIG, D. P. and NYHOLM, R. , The nature of the metal-ligand bond, Chelating Agents and Metal Chelates, Eds.

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An Introduction to Co-ordination Chemistry by D. P. Graddon, H. Taube, A. G. Maddock

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